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Oxidative coupling of thiols to disulfides using two trimethylammonium halochromates (VI), (CH3)3NH[CrO3X], (X= F,Cl) supported on alumina

Fahmideh Shabani1, Shahriare Ghammamy2*, Ali Hassanijoshaghani3


Mild and efficient method for the oxidative coupling of thiols by alumina supported trimethylammonium fluorochromate (TriMFC) and trimethylammonium chlorochromate (TriMCC) are reported.Alumina supported trimethylammonium fluorochromate and trimethylammonium chlorochromate are efficient and new reagents, which prepared easily and oxidized thiols to the corresponding disulfides quickly. The reactions performed cleanly and controlled to stop at the disulfide stage without overoxidation side products. The easy procedure, simple work-up, short reaction times, and excellent yields are another advantages of these reagents.


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  • 中国社会科学院
  • 谷歌学术
  • 打开 J 门
  • 中国知网(CNKI)
  • 引用因子
  • 宇宙IF
  • 研究期刊索引目录 (DRJI)
  • 秘密搜索引擎实验室
  • ICMJE

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