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Photochemical Ligand Exchange Reaction of Nitrosyl Pentacyanoferrate (II) Using Thiourea

Mayank R. Mehta, Vipul P. Prajapati and Tarun Patel


Sodium nitroprusside contains cyanide ligand that cannot be so easily replaced chemically. An effort has been made to substitute this ligand by another ligand like thiourea. The progress of this photochemical reaction has been observed spectrophotometrically and the product was isolated and characterized. The effect of different parameters like pH, intensity of light concentration of sodium nitroprusside and ligand concentration on the yield of this substitution reaction has been studied. A tentative mechanism for this reaction has been proposed


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  • 中国社会科学院
  • 谷歌学术
  • 打开 J 门
  • 中国知网(CNKI)
  • 引用因子
  • 宇宙IF
  • 研究期刊索引目录 (DRJI)
  • 秘密搜索引擎实验室
  • ICMJE

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